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The sustainability of industrial hemp: a literature review of its economic, environmental, and social sustainability.

hemp paper case study

1. Introduction

2. methodology, 3.1. industrial hemp plant, 3.2. parts and uses for the industrial hemp plant, 3.3. sustainability of industrial hemp, 3.3.1. hemp economic sustainability.

  • A wide range of products can be made with hemp.
  • Hemp products account for a small percentage of food, textiles, personal care products, pharmaceuticals, and nutraceuticals sales in the U.S. and worldwide, but sales are growing quickly.
  • Despite the falling production of hemp worldwide, due to its association with marijuana since the 1950s, business and policy changes, infrastructure investment, and improved production methods have led to a rebound in hemp production over the past decade.

3.3.2. Hemp Environmental Sustainability

  • The criteria were set based on the author’s familiarity with the topic.
  • There is a limitation to the author’s knowledge of a wide range of crops and criteria.
  • There may be some criteria that deserve to be heavily weighted, depending on location (e.g., irrigation may be more critical in areas with low water availability).

3.3.3. Hemp Social Sustainability

4. conclusions, author contributions, conflicts of interest.

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Kaur, G.; Kander, R. The Sustainability of Industrial Hemp: A Literature Review of Its Economic, Environmental, and Social Sustainability. Sustainability 2023 , 15 , 6457. https://doi.org/10.3390/su15086457

Kaur G, Kander R. The Sustainability of Industrial Hemp: A Literature Review of Its Economic, Environmental, and Social Sustainability. Sustainability . 2023; 15(8):6457. https://doi.org/10.3390/su15086457

Kaur, Gurinder, and Ronald Kander. 2023. "The Sustainability of Industrial Hemp: A Literature Review of Its Economic, Environmental, and Social Sustainability" Sustainability 15, no. 8: 6457. https://doi.org/10.3390/su15086457

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Consumer response to hemp: A case study of Vermont residents from 2019 to 2020

Corresponding Author

Jane Kolodinsky

  • [email protected]
  • orcid.org/0000-0001-7322-0889

Community Development and Applied Economics, University of Vermont, Burlington, VT, USA

Correspondence

Jane Kolodinsky, Community Development and Applied Economics, University of Vermont, Burlington, VT, USA.

Email: [email protected]

Hannah Lacasse

  • orcid.org/0000-0002-4682-1168

Hemp has emerged as a novel crop and ingredient for sustainable products. If innovative hemp-based products are to succeed in the market, the surge of interest in production must be accompanied by information generation across the supply chain. At present, there is little knowledge on consumer behavior toward hemp and hemp-based products, and even less on how this behavior has changed since hemp's reintroduction to the production landscape of the United States in 2014. This study compares representative survey data of Vermont residents in 2019 and 2020 on their support for hemp production, and awareness and use of hemp-based products. Although the influence of demographic variables did not significantly change over time, our findings reveal structural change, with more respondents aware of and using hemp-based products in 2020 compared to 2019. These findings point to hemp's growing presence and acceptance in the marketplace, where consumers are more informed about or have greater access to hemp products. Despite the state's focus on cannabidiol production, Vermonters appear to be aware of and are purchasing a variety of hemp goods, such as clothing and paper.

1 INTRODUCTION

Hemp ( Cannabis sativa ) has reemerged in the market landscape of the United States as a sustainable crop and product alternative. The crop's floral, grain, and fiber material can act as substitutes for synthetic fossil fuel-based ingredients, and create thousands of value-added products (Das et al., 2017 ; Langeveld et al., 2010 ; Popular Mechanics Magazine, 1938 ). Hemp can serve as a low energy crop, whose biomass can provide a myriad of bioenergy outputs (Finnan & Styles, 2013 ; Papadopoulou et al., 2015 ; Rehman et al., 2013 ). These characteristics make hemp a viable input for a bioeconomy, where renewable resources serve as the basis for value-added materials, products, and energy (Amaducci et al., 2015 ; McCormick & Kautto, 2013 ; Tang et al., 2017 ).

Hemp production was reintroduced to the United States with the passing of the 2014 Farm Bill, which allowed for state-based research and pilot programs ( Legitimacy of Industrial Hemp Research , 2014 ). The federal legalization of hemp in 2018 triggered national interest in its production and commercialization ( Agriculture Improvement Act of 2018 , 2018 ). The U.S. Department of Agriculture (USDA) reports that hemp acreage increased by nearly 350% from 2018 to 2019, with a focus on floral harvest for essential oil and cannabidiol (CBD) production (Mark et al., 2020 ). CBD has been an appealing production prospect due to rising consumer demand and high economic returns (Mark et al., 2020 ; Mark & Snell, 2019 ). However, the report also points to the uncertainty of land availability, oversupply, market transparency, risk management, and government regulation that this nascent sector must manage in the coming years. An absence of peer-reviewed research and data on the hemp consumer market nationally have been identified as an active hurdle to addressing these challenges (Ellison, 2020 ; Mark et al., 2020 ). Knowledge on CBD demand is particularly crucial due to volatile prices and rigorous regulation (Mark et al., 2020 ). For some states, such as Kentucky and Colorado, the CBD market has already experienced price volatility since hemp's legalization, with biomass prices peaking in July of 2019 at approximately $4.50 per percentage CBD per pound and dropping in January of 2020 to nearly 50 cents per percentage CBD per pound, threatening the resilience and longevity of producers (Mark, 2020 ). Thus, this study seeks to contribute to this gap in literature through an analysis of Vermont residents' behavior toward hemp and hemp-based products, including CBD products, over time.

Vermont serves as a comparable lens from which to view hemp's development in the United States. The state's percentage growth for number of registrations and registered hemp acres from 2016 to 2019 is approximate to that of the United States as a whole (Figures 1 and 2 ). Vermont also shares similar production concerns expressed by the rest of the country, including fair pricing and market saturation (McCallum, 2019 ; Wallace Allen, 2019 ). By the end of the 2019 harvesting season, 50% of surveyed hemp growers did not have a buyer for their material (Vermont Agency of Agriculture Food & Markets, 2019 ). Given these challenges, registered acres and registrations have dropped from 2019 to 2020 in Vermont (Figures 1a and 2a ).

Details are in the caption following the image

Insight into consumer demand and behavior toward hemp-based products is critical to help direct risk management and production strategies for growers and processors (Mark et al., 2020 ). Understanding the hemp consumer will play an important role in constructing a robust and resilient industry. A 2019 survey identified market demand as the most highly anticipated research category for hemp producers (Ellison, 2020 ) and the USDA notes that market and economic research on national hemp production is absent (Mark et al., 2020 ). Although producers have been quick to adopt this innovative crop, there is scant peer-reviewed research on how consumers have responded to its resurgence. Research on internet searches in the United States reveals a rise in searches for CBD between 2014 and 2018, with search volumes increasing by 160% from 2017 to 2018 (Leas et al., 2019 ). Kolodinsky et al. ( 2020 ) find that consumer demand for hemp-based products in Vermont may extend beyond CBD products, including clothing and personal care products. However, this is the only published, peer-reviewed literature on consumer behavior toward hemp in Vermont and in the United States more broadly to date. Industry derived data on consumer demand for hemp are largely focused on CBD products, with men and older consumers more likely to consumer CBD products (New Frontier Data, 2020a ). Kim and Mark ( 2018 ) have also analyzed Nielsen Consumer Panel data to evaluate the influence of demographics on cereal, nuts, vitamins, and medications. Given hemp's historic ties to marijuana, indication of consumer acceptance of hemp and their response to all types of hemp products on the market is critical to allow for educated production and marketing decisions (Malone & Gomez, 2019 ). This study builds this knowledge base through a comparison of 2019 and 2020 survey data of Vermont consumers on their support for hemp production, and familiarity with and use of hemp-based products. Given the timing of hemp's federal legalization, Vermont's hemp harvest period, and the data collection period, this study represents a comparison of consumer behavior between the 2019 and 2020 growing seasons.

2 MATERIALS AND METHODS

2.1 materials.

This study analyzes data collected by the University of Vermont's Center for Rural Studies through a statistically representative telephone survey of Vermont residents. Approved by the Institutional Review Board at the University of Vermont, data were collected in February and March of both 2019 and 2020. Trained interviewers conducted the survey using computer-aided telephone interviewing. Respondents were chosen through random sampling from a list of Vermont landline and cell phone numbers. Respondents were randomly selected each year of data collection; thus, these data serve as cross-sectional samples where the identities of individual respondents cannot be discerned. To participate in the survey, respondents had to be current residents of Vermont and 18 years or older. Complete responses required for the logistic regressions conducted in this study ranged from 934 to 946 and results have a margin of error ranging from ±3.204% to ±3.184% with a confidence level of 95%. IBM ® SPSS ® Version 26 was used to conduct all statistical analyses.

2.2 Methods

This study characterizes consumer behavior toward hemp and hemp products through three survey questions: support for industrial hemp production, familiarity with hemp-based products, and use of hemp-based products. Support for hemp production was collected through a five-point Likert scale, ranging from strongly opposed to strongly supportive. For the purposes of this study, this variable was recoded into those who are somewhat or strongly supportive compared to all other responses. Respondents were asked whether they were familiar with hemp CBD oil, hemp clothing or shoes, and hemp paper. General familiarity is defined as whether respondents indicated they were familiar with at least one of these three product categories. Respondents were also asked whether they use hemp-based products, including hemp CBD oil and hemp clothing. General familiarity is defined as whether respondents indicated that they use at least one category of product.

Sociodemographic data were collected for both survey years (Table 1 ). Age was measured continuously. Education is categorically measured into six levels of education. This sample appears to be more highly educated than Vermont census indications; those with a bachelor's degree or higher being greater in our sample (53.4%) than state estimates (37.3%; United States Census Bureau, 2019 ). Female representation is higher in our sample (59.2%) than census estimates (50.6%; United States Census Bureau, 2019 ). Median household income for the state is $60,076 and those with an annual income of $50,000 or higher in our sample are 65.8% (United States Census Bureau, 2019 ). In order to determine urban vs. rural influence, a location variable was created to compare those residing in Chittenden County, the most populous Vermont county, with everyone else (Vermont Department of Health, 2019 ). Both our sample and census estimates indicate that 26% of Vermont residents reside in Chittenden County (United States Census Bureau, 2019 ).

Variable Definition 2019 2020 Cumulative
% % %
Age Continuous 58.7 638 54.6 515 56.9 1153
Education Less than high school diploma 3.3 646 2.5 525 2.9 1171
High school diploma or GED 18.7 17.7 18.3
Some college completed 16.9 16.2 16.6
Associates or technical degree 9.1 8.6 8.9
Bachelor's degree 28.0 28.6 28.3
Postgraduate or greater 24.0 26.5 25.1
Gender Female 63.2 650 54.2 520 59.2 1170
Income Less than $25,000/year 12.8 553 12.9 457 12.9 1010
$25,000–$50,000/year 20.8 21.9 21.3
$50,000–$75,000/year 22.4 18.4 20.6
$75,000–$100,000/year 16.1 15.3 15.7
Greater than $100,000/year 27.8 31.5 29.5
Political affiliation Republican 15.5 611 14.6 501 15.1 1112
Democrat 30.0 27.9 29.0
Independent 29.6 31.9 30.7
Progressive 7.7 8.0 7.8
Not politically affiliated 17.2 17.6 17.4
Location Chittenden County 27.2 680 24.4 537 26.0 1217
  • a Mean value.

urn:x-wiley:17571693:media:gcbb12786:gcbb12786-math-0001

The resulting LR statistic has an approximate chi-square distribution under the null hypothesis, with a critical value of 95%. If we fail to reject the null hypothesis that the restricted model was significantly different from the unrestricted model, then only the restricted model was analyzed to determine the presence of statistically significant structural change from 2019 to 2020.

The majority of respondents in both survey years are supportive of hemp production in Vermont; however, there is no statistically significant association between support and year (Table 2 ). Significantly more respondents are familiar with hemp-based products in 2020 compared with 2019 (85.3%) vs. 96.8%. The majority of respondents are familiar with hemp CBD oil and hemp clothing in both years, with significantly more being familiar in 2020. Familiarity with hemp paper has risen from 35.0% in 2019 to 61.6% in 2020. General use of hemp-based products has risen from 32.6% in 2019 to 54.7% in 2020. Use of hemp CBD and hemp clothing specifically have also risen from 2019 to 2020. All dependent variables for familiarity and use are significantly associated with year.

Year Supportive of hemp production Familiarity Use
General familiarity Hemp CBD oil Hemp clothing Hemp paper General use Hemp CBD Hemp clothing
% % % % % % % %
2019 75.9 0.000 85.3 45.985 78.5 70.250 70.4 63.021 35.0 85.529 22.1 66.039 15.2 62.644 9.8 50.404
2020 76.0 96.8 95.3 89.2 61.6 44.1 34.8 25.1
  • Degrees of freedom for all variables are equal to 1.
  • Abbreviation: CBD, cannabidiol.
  • *** Significant at p  < 0.001.

Likelihood ratio test results for those supportive of hemp production in Vermont lead us to fail to reject the null hypothesis that the influence of demographic variables on hemp support did not significantly change over time ( χ 2 (16) = 16.539, p  = 0.420). Logistic regression results for the restricted model reveal that year is not a statistically significant predictor of hemp support ( p  = 0.718; Table 3 ). Six sociodemographic variables are significantly associated with support. Age is negatively associated with hemp support, while income of $50,000–$75,000 per year, income of $75,000–$100,000 per year, Democrat affiliation, Independent affiliation, and Progressive affiliation are positively associated with hemp support.

Variable Definition Exp ( ) SE
Age Continuous 0.989 0.006 1
Education Less than high school diploma
High school diploma or GED 0.623 0.524 1
Some college completed 1.024 0.536 1
Associates or technical degree 1.156 0.570 1
Bachelor's degree 1.182 0.533 1
Postgraduate or greater 0.729 0.540 1
Gender Female 0.816 0.173 1
Income Less than $25,000/year
$25,000–$50,000/year 1.426 0.273 1
$50,000–$75,000/year 1.806 0.288 1
$75,000–$100,000/year 2.443 0.337 1
Greater than $100,000/year 1.266 0.282 1
Political affiliation Republican
Democrat 2.629 0.249 1
Independent 2.821 0.247 1
Progressive 6.277 0.455 1
Not politically affiliated 0.946 0.253 1
Location Chittenden County 0.862 0.190 1
Year 2020 0.942 0.166 1
Constant 3.070 0.657 1
  • a Reference category.
  • * Significant at p  < 0.050;
  • ** Significant at p  < 0.010;

Results for the LRT for general familiarity with hemp-based products lead us to fail to reject the null hypothesis that the influence of demographic variables on general familiarity with hemp did not significantly change over time ( χ 2 (16) = 25.873, p  = 0.060). Logistic regression results for the restricted model reveal that year is a statistically significant predictor of general familiarity ( p  = 0.001) (Table 4 ). Age and an income higher than $100,000 per year are also significant predictors of general familiarity. Older respondents are less likely to be generally familiar with hemp-based products than younger respondents by 0.943 percentage points ( p  < 0.001) and those with an income higher than $100,000 per year are 3.324 times more likely to generally familiar than those with an income of less than $25,000 per year ( p  = 0.001). Respondents in 2020 were 3.587 times more likely to be familiar with hemp-based products compared to 2019 ( p  < 0.050).

Variable Definition Exp ( ) SE
Age Continuous 0.943 0.012
Education Less than high school diploma
High school diploma or GED 1.202 0.524
Some college completed 1.278 0.536
Associates or technical degree 1.780 0.570
Bachelor's degree 2.395 0.533
Postgraduate or greater 4.128 0.540
Gender Female 0.886 0.173
Income Less than $25,000/year
$25,000–$50,000/year 1.799 0.273
$50,000–$75,000/year 1.951 0.288
$75,000–$100,000/year 1.556 0.337
Greater than $100,000/year 3.324 0.282
Political affiliation Republican
Democrat 0.878 0.249
Independent 1.401 0.247
Progressive 1.828 0.455
Not politically affiliated 0.753 0.253
Location Chittenden County 0.815 0.190
Year 2020 3.587 0.166
Constant 137.135 0.657

Results from the LRTs for familiarity with hemp CBD oil, hemp clothing, and hemp paper lead us to fail to reject all null hypotheses. The influence of demographic variables on familiarity with hemp CBD oil ( χ 2 (16) = 20.095, p  = 0.220), hemp clothing ( χ 2 (16) = 11.300, p  = 0.790), and hemp paper ( χ 2 (16) = 12.058, p  = 0.740) did not significantly change over time. Results of the logistic regressions of the restricted models for familiarity with each hemp product were significantly associated with year, with respondents being 3.909 ( p  < 0.001), 2.824 ( p  < 0.001), and 2.408 ( p  < 0.001) times more likely to be familiar with hemp CBD oil, hemp clothing, and hemp paper, respectively (Table 5 ). Demographics had inconsistent significant associations with familiarity across specific hemp-based products. Older respondents are 0.960 ( p  < 0.001), 0.975 ( p  < 0.001), and 0.965 ( p  < 0.001) percentage points less likely to be familiar with hemp CBD oil, hemp clothing, and hemp paper, respectively, than younger respondents. Education is significantly associated with familiarity with hemp clothing: those with a bachelor's degree or a postgraduate degree or greater are 3.783 ( p  = 0.010) and 4.892 ( p  = 0.003) times more likely to be familiar with hemp clothing than those with less than a high school diploma. Females are less likely to be familiar with hemp paper than males by 0.677 percentage points ( p  = 0.008). Those with an income between $25,000 and $50.000 per year are 2.355 ( p  = 0.017) times more likely to be familiar with hemp CBD oil than those with an income of less than $25,000 per year. Respondents with an income higher than $100,000 per year were 2.559 ( p  = 0.020) and 1.938 ( p  = 0.036) times more likely to be familiar with hemp CBD oil and hemp clothing, respectively. Respondents who identified as Progressives were 2.002 ( p  = 0.030) times more likely to be familiar with hemp paper than Republican respondents.

Variable Definition Hemp CBD oil Hemp clothing Hemp paper
Exp ( ) SE Exp ( ) SE Exp ( ) SE
Age Continuous 0.960 0.009 0.975 0.006 0.965 0.005
Education Less than high school diploma
High school diploma or GED 1.168 0.657 1.599 0.500 0.996 0.504
Some college completed 1.201 0.666 2.382 0.512 1.782 0.508
Associates or technical degree 2.106 0.745 2.502 0.549 0.924 0.532
Bachelor's degree 1.912 0.675 3.783 0.515 1.200 0.502
Postgraduate or greater 2.128 0.697 4.892 0.536 1.148 0.510
Gender Female 0.989 0.244 1.228 0.190 0.677 0.148
Income Less than $25,000/year
$25,000–$50,000/year 2.355 0.359 1.543 0.287 0.785 0.253
$50,000–$75,000/year 1.662 0.352 1.352 0.293 0.841 0.259
$75,000–$100,000/year 1.675 0.411 1.623 0.342 0.763 0.281
Greater than $100,000/year 2.559 0.403 1.938 0.316 0.655 0.257
Political affiliation Republican
Democrat 1.371 0.343 1.097 0.279 0.935 0.229
Independent 1.565 0.338 1.439 0.276 1.287 0.223
Progressive 3.603 0.675 2.047 0.475 2.002 0.319
Not politically affiliated 1.064 0.379 0.792 0.295 0.611 0.256
Location Chittenden County 1.001 0.275 0.960 0.216 0.966 0.165
Year 2020 3.909 0.287 2.824 0.201 2.408 0.143
Constant 17.993 0.921 2.566 0.665 6.155 0.606

Likelihood ratio test results for general use of hemp-based products lead us to fail to reject the null hypothesis that the influence of demographic variables on general use did not significantly change over time ( χ 2 (16) = 15.322, p  = 0.500). Logistic regression results for the restricted model reveal that year is a statistically significant predictor of general use of hemp products ( p  < 0.001; Table 6 ). Two categories of demographic variables are significant predictors of general hemp use: respondents with an Independent and a Progressive political orientation are 1.861 ( p  = 0.005) and 2.640 ( p  = 0.002) times more likely to use hemp products, respectively, than Republican respondents.

Variable Definition General use Hemp CBD oil Hemp clothing
Exp ( ) SE Exp ( ) SE Exp ( ) SE
Age Continuous 0.992 0.005 0.995 0.005 0.988 0.006
Education Less than high school diploma
High school diploma or GED 0.600 0.474 1.272 0.606 0.595 0.627
Some college completed 0.895 0.476 1.354 0.606 0.518 0.632
Associates or technical degree 0.823 0.503 1.466 0.631 0.429 0.681
Bachelor's degree 0.789 0.471 1.284 0.599 0.616 0.614
Postgraduate or greater 0.738 0.480 0.920 0.609 0.710 0.623
Gender Female 1.165 0.146 1.148 0.166 1.245 0.194
Income Less than $25,000/year
$25,000–$50,000/year 0.690 0.248 1.150 0.290 0.907 0.365
$50,000–$75,000/year 1.015 0.252 1.470 0.293 1.734 0.350
$75,000–$100,000/year 1.063 0.274 1.356 0.319 1.639 0.376
Greater than $100,000/year 0.873 0.251 1.254 0.294 1.353 0.352
Political affiliation Republican
Democrat 1.278 0.228 1.373 0.268 1.700 0.344
Independent 1.861 0.221 1.746 0.257 2.485 0.330
Progressive 2.640 0.312 2.236 0.342 3.445 0.405
Not politically affiliated 1.191 0.252 0.842 0.307 1.033 0.396
Location Chittenden County 1.015 0.161 1.317 0.179 1.057 0.210
Year 2020 2.295 0.140 2.884 0.162 3.103 0.192
Constant 0.779 0.577 0.108 0.724 0.129 0.787

We also reject the null hypothesis that the influence of sociodemographic variables on use of both hemp CBD oil ( χ 2 (16) = 7.217, p  = 0.970) and hemp clothing ( χ 2 (16) = 21.058, p  = 0.180) did not significantly change between 2019 and 2020. Logistic regression results for the restricted models for use of hemp CBD oil and hemp clothing were both significantly associated with year, with respondents being 2.884 ( p  < 0.001) and 2.103 ( p  < 0.001) times more likely to use these products in 2020 compared to 2019 (Table 6 ). For use of hemp CBD oil, respondents with an Independent political orientation were 1.746 times more likely to use hemp CBD oil compared to Republican respondents. For use of hemp clothing, respondents with Progressive and Independent political orientations were 2.485 ( p  = 0.006) and 3.445 ( p  = 0.002) times more likely to use hemp clothing, respectively.

4 DISCUSSION

Hemp has been reintroduced to the production and market landscapes of the United States. Registered acreage is growing, processors are investing, and more innovative products are being researched and becoming accessible to consumers. Hemp has been touted as a sustainable and environmentally friendly crop, with thousands of potential products. However, the time and attention given to hemp have not been accompanied by evidence-based, peer-reviewed research on consumer segmentation and demand for hemp-based products. Now that hemp has been federally legalized and theoretical limitations, such as price volatility, oversupply, and risk management, are now experienced challenges, such information is critical to inform production and marketing strategies to enable a robust and resilient sector. Through a case study of Vermont residents, results offer a reference for consumer response and behavior toward hemp in the first year of federal legalization.

Results reveal that the association between demographic characteristics and support, awareness, and use of hemp and hemp-based products has not significantly changed over time. However, significant associations with demographic variables and support, awareness, and use exist across both survey years. Those with higher incomes were more likely to support hemp production than those in the lowest income bracket. This may be reflective of a “not in my backyard” mentality, where those with higher incomes are able to avoid proximity to hemp fields due to odor or drug-related concerns, while lower income households may not have that ability (Németh & Ross, 2014 ). Those in the highest income bracket were also more likely to be generally familiar with hemp products. This may support previous studies that find income is positively associated with hemp purchases, indicating that hemp-based products are more expensive compared to conventional products (Kim & Mark, 2018 ). Use is not significantly associated with income and may indicate that there is a more complex relationship with hemp consumption and demographic variables. When compared to other industry data, this study supports findings regarding high consumer awareness of CBD products (New Frontier Data, 2020b ). This study does not support industry findings that gender is a significant predictor of hemp CBD use (New Frontier Data, 2020a ).

Independent, Progressive, and Democrat respondents were more likely to support hemp production than Republican respondents. Progressive and Independent respondents were also more likely to be general users of hemp-based products, as well as users of hemp clothing. Independent political orientation was associated with use of hemp CBD oil. These results support findings in a 2019 case study of Vermont residents, and further demonstrate continued political polarization of hemp due to the stigma related to drugs and marijuana (Kolodinsky et al., 2020 ). Public education on hemp's unique traits and distinction from marijuana may help to build confidence in consumers unwilling to try hemp-based products due to this false stigma. Age was the only consistent demographic predictor of hemp familiarity, both generally and with hemp CBD oil, hemp clothing, and hemp paper. Older respondents are less likely to be familiar with these products than younger respondents. This points to segmented education opportunities to broaden knowledge of hemp products in order to grow their accessibility and use in the market.

Noteworthy is the finding that respondents were more likely to be general users of hemp, as well as specific users of hemp CBD oil and hemp clothing in 2020 compared to 2019. This could be the result of the widespread introduction and adoption of hemp-based products into the market. However, this may also be due to differences in recall strategy between survey years, where the 2020 survey provides a list of hemp products based on responses to the open-ended 2019 survey. These recall differences are a limitation of this study.

This study finds that awareness and use of hemp-based products among Vermont respondents have experienced structural change over time in its first 2 years of federal approval. Although demographic variables did not significantly change over time, we find political affiliation to be a significant predictor of hemp use. Remaining demographic characteristics were found to be inconsistent predictors of hemp familiarity and use. These findings support previous research and contribute to the indication that consumer preference for hemp-based products may be influenced by attitudes and opinions (Kolodinsky et al., 2020 ). Future research should include information on consumer motivations for purchasing hemp products that go beyond demographic characteristics and reach a sample wider than a single state. USDA grant 2020-67024-30955- Economic Impacts of the Hemp Industry: Opportunities for Rural Development provides funding to conduct a national consumer study in 2021. Recommendations derived from this study will be contributed to the creation of the survey.

Open Research

Data availability statement.

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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  • DOI: 10.1093/AEPP/PPZ001
  • Corpus ID: 159385994

Hemp in the United States: A Case Study of Regulatory Path Dependence

  • Trey Malone , Kevin D. Gomez
  • Published in Applied Economic Perspectives… 1 June 2019
  • Law, Medicine, Political Science
  • Applied Economic Perspectives and Policy

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Title: Marketing potentials of ecofriendly paper products: case study

Authors : Alan D. Smith

Addresses : Department of Marketing, Robert Morris University, 6001 University Blvd, Moon Twp, PA 15108, USA

Abstract : The ecofriendly or green revolution has greatly evolved, especially from a marketing perspective. Hemp products, especially food protein and non-food products (paper) may well be the next evolution ecofriendly supply chain strategies. Through the use of a case study approach, hemp as a source for paper that results in a quicker cycle time and is more climate change friendly than trees, may well turn out to be a part of a sustainable supply chains. Besides the direct environmental impact, paper pulp requires a number of chemical treatments in order for it to have longevity as a product. The innovative solution that can challenge the traditional monopoly is hemp-based, ecofriendly paper products. Hemp paper is a natural alternative to tree-based paper and is an obvious upgrade from the latter. Recent federal degradations have made this ecofriendly resource extremely attractive.

Keywords : cash crops; hemp paper; ecofriendly; green products; supply chain management; SCM; sustainable supply chain integration; SSCI; sustainability.

DOI : 10.1504/IJBFMI.2023.129853

International Journal of Business Forecasting and Marketing Intelligence, 2023 Vol.8 No.2, pp.157 - 178

Received: 20 Jul 2022 Accepted: 26 Jul 2022 Published online: 31 Mar 2023 *

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Hemp and Its Derivatives as a Universal Industrial Raw Material (with Particular Emphasis on the Polymer Industry)—A Review

Associated data.

No data are available while the first author was a doctoral candidate in the Interdisciplinary Doctoral School at the Lodz University of Technology, Poland.

This review article provides basic information about cannabis, its structure, and its impact on human development at the turn of the century. It also contains a brief description of the cultivation and application of these plants in the basic branches of the economy. This overview is also a comprehensive collection of information on the chemical composition of individual cannabis derivatives. It contains the characteristics of the chemical composition as well as the physicochemical and mechanical properties of hemp fibers, oil, extracts and wax, which is unique compared to other review articles. As one of the few articles, it approaches the topic in a holistic and evolutionary way, moving through the plant’s life cycle. Its important element is examples of the use of hemp derivatives in polymer composites based on thermoplastics, elastomers and duroplasts and the influence of these additives on their properties, which cannot be found in other review articles on this subject. It indicates possible directions for further technological development, with particular emphasis on the pro-ecological aspects of these plants. It indicates the gaps and possible research directions in basic knowledge on the use of hemp in elastomers.

1. Introduction

The polymer industry has grown smoothly and continuously for many decades. Polymers and composites based on them have become one of the basic utility materials, next to wood, concrete, glass or metals, for the production of simple everyday objects, through elements of larger structures, such as vehicles and buildings, to modern and very complex parts, specialized equipment and even spaceships. The wide range of polymers and their properties, which can be further changed by the use of other materials and ingredients, give us as scientists an infinite field for the development of these versatile materials, limited only by our imagination. All this makes polymer composites a versatile product. However, they have their pros and cons, as with any other product. One such ambiguous property is its high durability. As consumers, we most often want polymer materials to have as much as possible, but after use, a problem arises. What to do with such materials? Unfortunately, many of the plastics used so far do not break down too quickly [ 1 ]. For some of them, this process can take hundreds of years. For this reason, the growing awareness of researchers, consumers and ecologists put pressure on the development of the field of science dealing with polymer materials and biocomposites, which, in particular, should be characterized by a high biodegradability or compostability potential [ 2 , 3 , 4 , 5 ]. One of the approaches to the development of environmentally friendly polymer materials is the use of substances derived from fauna and flora in composites. An even better solution is to use materials that are typical production waste from other industrial sectors. In this article, we focus on presenting just such an approach. This review focuses on the material of plant origin, and in particular on hemp and all its derivatives that have or may have potential industrial applications, including with particular emphasis on polymers for the creation of biocomposites.

The cannabis plants originally come from Central and East Asia, which later spread to the rest of Asia, and in subsequent periods also to Europe [ 6 ]. They are one of the earliest used and cultivated plants in human history. Initially, they were used as plants for the production of food, but also as fiber and medicinal substances. Due to different purposes, man has become interested in two basic types of cannabis, also known as Cannabis Sativa fibrous cannabis and Cannabis Indica , with a higher content of narcotic compounds. The paleontological records indicated in the research contain information about the discovery of cannabis fragments used by primitive humans at least 10,000 years ago [ 7 ]. Based on the collected biological data, it can be concluded that cannabis grows best in temperate climates, where optimal temperatures for growth are between 15 and 27 degrees Celsius. These plants grow best in permeable soils with high fertility and in slightly moist or periodically dry areas. Such conditions for good development can be found mainly on the shores of water reservoirs. Due to their round shape, the seeds are not very well carried by the wind. Rather, cannabis has developed a mechanism that uses birds and other animals to carry their seeds because they are high-value food. Probably the seeds were used as the first parts of the cannabis plant. They were mainly used as food. The next step was to process the stems into strings, fabrics and fibers. It was one of the most important steps in the progress of mankind, which allowed for the production of combining skins, furs and the creation of fabrics or everyday objects, such as baskets, which allowed for faster expansion of people into areas previously inaccessible, cool postglacial. The development of this technology allowed the transition from a nomadic to a more sedentary lifestyle. Further technological advances allowed the production of textile fabrics from fibers and more and more complex elements. Hemp material was widely used in the Columbian era because without hemp fibers, it would not have been possible to create such strong and durable ropes and masts on ships that allowed long and distant sea journeys and the discovery of new lands [ 8 ]. Only the development of the cotton industry and then the large-scale plastics has led to the marginalization of the hemp share so far. Currently, these versatile plants are making a comeback thanks to the multitude of possible uses with an ecological approach at the same time. These aspects make it one of the most interesting plants indicated as the future of agriculture in the European Union [ 9 ]. This article is a broad overview of cannabis, its structure, composition and properties of individual fractions and, importantly, describes the use of these very important plants in various sectors of the economy, from the food industry, construction and pharmacology, through the automotive industry, with an emphasis on the polymer industry. It is an extensive work containing the most important information on the material and physicochemical properties of this important pro-ecological, multifunctional plant. This review article has an evolutionary structure that resembles the life cycle. This text begins with the characteristics of the historical outline of the use of cannabis for human life, in the following chapters the structure of plants as well as the chemical composition and properties of individual anatomical parts of plants are described. The following chapters describe the ways of using hemp broken down into individual industries, with the final development of the topic of the use of the polymer industry with the division into thermoplastic polymers, elastomers and duroplasts, which are the main topic of our research. It is worth noting that the prepared review is one of the few prepared texts that contain a comprehensive approach to the topic, as it is characterized not only by the composition of individual hemp derivative fractions but also contains a general overview of the use in various industries, taking into account the latest technological innovations of each of them. It is also the only one that describes the use of hemp materials in polymeric materials in more detail, highlighting the knowledge gap regarding the use of fibers and other hemp derivatives in thermosets and, above all, in elastomers as research in this area is insufficient. We believe that this article will be a very good tool to start spreading knowledge about cannabis, improve knowledge about it, and change the attitude in the community, and in particular, for it to be appreciated by researchers, technologists and entrepreneurs.

2. Characteristics of Hemp Plants

2.1. structure and composition, 2.1.1. hemp fibres.

Cellulose fibers are the most common biopolymer in the world; their production in 2004 was about 10 11 tons. They are widely used by man in a variety of technological processes due to their abundance, common occurrence and excellent physicochemical properties [ 10 ]. Cellulose belongs to the group of polysaccharides, i.e., polysaccharides such as starch, chitin or dextrins. It is also a polyacetal containing glycosidic bonds linking individual sugar residues, forming long linear polymer chains [ 11 ]. This homopolymer is produced indirectly by plants through photosynthesis from the substrates, which include water and carbon dioxide [ 12 ]. During its synthesis in plant cells, there is also the necessary energy from sunlight. The cellulose itself is used by plants mainly as a construction material in the construction of conductive tissues in wood. It occurs mainly in stems. It is a solid with a fibrous structure, which consists of crystalline and amorphous areas; thus, it can be characterized as semicrystalline [ 13 ]. It has no smell or taste and does not dissolve in cold or warm water and organic solvents [ 14 ]. As a polymer of natural origin, cellulose has a number of distinguishing properties among other widely used materials. In short, you can characterize it as:

  • Homopolymer that comes from natural sources;
  • It has a zero-carbon balance for the environment due to its use in its synthesis, carbon dioxide;
  • It is a biopolymer derived from renewable sources, biodegradable, providing good environmental and biological characteristics and high bioorganic compatibility [ 15 , 16 , 17 ];
  • It is highly pure and non-toxic [ 18 ];
  • It is characterized by good mechanical strength, which is why it is used as one of the basic natural construction materials [ 19 ].

During biodegradation processes, microorganisms decompose biopolymers, and cellulose as an example of a polysaccharide, under aerobic conditions into water, carbon dioxide and biomass, and under anaerobic conditions into CH 4 , biomass and water [ 20 ].

Cellulose is a linear high molecular weight homopolymer. Its structure includes sections composed of D-glucose, and more specifically β-D-glucopyranose, connected to each other by β-1,4-glycosidic bonds. Native cellulose up to 10 thousand residues β-anhydroxyglucose linked together to form a long chain molecule. This means that the mass of such a molecule is over 1.5 million units. However, the unit length of β-anhydroxyglucose is 0.515 nm, i.e., 5.15 Å. It follows that the total length of the natural cellulose molecule is approximately 5 µm. The cellulose pulp and filter paper used usually contain particles with a degree of polymerization from 500 to 2.1 thousand [ 21 , 22 ]. Each β-anhydroxyglucose unit in the cellulose chain has a chair configuration with hydroxyl groups in equatorial positions and with hydrogen atoms in axial positions. The chair-shaped conformation of the chain (poly-1,4-D-glucosan) is shown in Figure 1 . It can be seen that the unit part of the chain is rotated around its main axis by 180°, resulting in an unrestricted rope configuration with minimal steric hindrance. The glycosidic bonds act similarly to the functional group, which, together with the hydroxyl groups, determines the chemical properties of cellulose. All significant chemical reactions take place precisely in the area of the glycosidic bond or the hydroxyl group. Each of the heterocyclic rings has the following groups:

  • Primary-CH 2 -OH;
  • Two secondary hydroxyl groups-OH.

An external file that holds a picture, illustration, etc.
Object name is materials-15-02565-g001.jpg

The chair conformation of β-anhydroxyglucose units in the cellulose chain.

The nature of cellulose, and more specifically its chemical, physical and mechanical properties, as well as the fibrous structure, we can relate to its molecular structure. Analogously to other hydrophilic linear polymers, individual cellulose molecules combine together to form a fibril or protofibril about 10 nm in length, 4 nm in width and about 3 nm thick. Unit distribution of cellulose chains is oriented parallel to each other and tightly connected by numerous intermolecular hydrogen bonds. The structure that makes up the cellulose fiber is hierarchical. The smallest basic microfiber building unit and the macrofiber is fibril. Many such structures collectively aggregate into long, thin bundles to form a microfiber. They, on the other hand, form macrofibrils in greater numbers and then fibers [ 23 , 24 , 25 , 26 , 27 , 28 ]. The crystalline regions of the linear cellulose chains are laterally linked by hydrogen bonds. They build a kind of mesh that extends across the entire cross-section of the microfiber. The crystalline regions are separated from each other by a layer of cellulose molecules, the arrangement of which is not specifically oriented towards each other, creating spaces characterized by amorphous or otherwise paracrystalline domain. The disordered area allows the degradation of the polymer chain with an aqueous solution of a strong acid. The amorphous portions of the fiber can occur naturally and can also be produced during mechanical degradation. The length of the molecule after acidolysis is variable and depends on the origin of the cellulose. However, the process itself leads to an even degree of polymerization in the obtained micelles or microcrystals [ 29 , 30 , 31 , 32 , 33 , 34 ].

The list of the initial stages of cellulose fiber degradation is presented, which can be described as follows:

  • An intact fiber-containing crystalline and amorphous regions, with frayed ends at the periphery consisting of a paracrystalline region of cellulose, lignocellulosic or hemicellulose;
  • Initial attack on regions with an amorphous structure;
  • There will remain residual microcrystallites and decomposition of the remaining free short chain fragments;
  • Attack on a crystalline region.

In the literature, there is a division of native cellulose into two crystal structures:

  • I α with the structure of a triclinic unit cell;
  • I β monoclinic unit cell structure.

Natural cellulose, derived from green plants and wood, contains a mixture of both crystal structures. However, it is primarily the characterization structure of a monoclinic unit cell. For example, cotton or ramie contains as much as 77% of it in their structure. On the other hand, the one derived from algae and bacteria has a higher content of the triclinic form. The more stable thermodynamic form of this biopolymer is I β because I α cellulose is transformed by hydrothermal treatment in alkaline solutions or by heat treatment in an inert gas atmosphere at 280 °C into the β form.

It is possible to recognize both structures by means of the 13 C-NMR test, while the correlation of this test with the absorption coefficient of the FT-IR spectrum is also performed using the following formula [ 24 , 35 , 36 , 37 , 38 , 39 ]:

  • A 710 absorption intensity at the wavenumber of 710 cm −1 ;
  • A 750 absorption intensity at the wavenumber of 750 cm −1 .

Cellulose has several crystalline forms, which may change from one another by simple technological unit operations.

Hemp is one of the main crops grown for its fiber. These fibers very quickly grow up to several mm a day during the intense growth phase. Primaries can reach a length of about 15 mm with a spread from a few to even more than 50 mm, as described in the work of Mussing et al. After the intensive growth phase, the cell walls are lignified and the cellulose content increases. This step leads to a mechanical strengthening of the fibers, in particular their stiffness. The length, chemical composition and properties of the fibers strongly depend on the variety and conditions in which the plant has grown. Compared to other plants, fibrous hemp is characterized by a high content of cellulose from 70 to 74% (including the one with a high degree of crystallinity) and hemicellulose, about 15–20%, but it has a limited amount of lignin, which usually 3.5%, but does not exceed 5.7%. The pectin content is usually around 0.8%, and the fat and wax content is 1.2–6.2% [ 40 , 41 , 42 ]. The amount and ratio of these components may vary depending on the degree of purification with NaOH. In the case of mechanical properties, it is difficult to determine individual values for individual fibers due to their short length. However, the length reported in most literature sources ranges from 5 to 55 mm, the crystallinity index is indicated as 55%, the diameter is in the range of 10.9 to 42 micrometers, and the density is about 1.5 g/cm 3 . As for Young’s modulus, it varies significantly from 14.4 to even 90 GPa, as does the breaking strength 285–1110 MPa and the elongation at break from 0.8 to 3.3% [ 43 ]. Large differences in the values in the sources result from irregularities in the diameter and length of the fiber, and the fact that a technical fiber was tested, which is characterized by a lower strength than a single, separated fiber with a shorter length, amounting to a few millimeters [ 44 ].

The analysis of the spectrum of infrared spectroscopy with Fourier transformation of hemp fibers shows the presence of several absorption bands characteristic of this material. These data were collected and described by Kaczmar et al. in the form of a table shown below [ 45 ]. Table 1 was also confirmed by other references than those mentioned in the above work.

Absorption signals of Fourier transform infrared spectroscopy for the spectrum of hemp fibers.

Name of the Function GroupWavenumber
[cm ]
Bibliographic
C-OH out-of-plane bending vibrations; C-C557[ ]
Stretch vibrations of the glucose ring;
C–H stretching vibrations outside the plane of the aromatic ring
895[ , ]
-OH; -COO900–1200[ ]
CO-O-CO1000–1100[ ]
C-O stretching vibrations; deformation of the C-H aromatic plane1030–1058[ , ]
The absorption band of hydroxyl compounds -OH1100[ , ]
C-O stretching vibrations; asymmetric bridge C-O-C stretching vibrations1158[ , ]
C-O; C=O; C-C-; COOH1100–1300[ ]
Acyl-oxygen CO-OR stretching vibrations in hemicelluloses; -CH 1245[ ]
C-H deformation vibrations; -OH bending vibrations1325[ ]
C-H bending vibrations related to the structure of cellulose and hemicellulose1369[ , ]
CH stretching vibrations related to the cellulose structure, vibrations of the bonds of the aromatic backbone1425–1426[ , , , ]
CH deformation vibrations; asymmetric bending vibrations from -CH and -CH groups1426–1463[ ]
C=C stretching vibrations in aromatic structures1508[ ]
C=C stretching of the aromatic ring1550[ ]
C=C unsaturated bonds;1592[ ]
COO (pectin)1650[ ]
-OH from absorbed water; C=C1653[ , , , ]
C=O stretching vibrations in uncoupled ketones and free aldehydes1736; 1718[ , , , , ]
CH stretching vibrations in methyl and methylene groups2896[ , , ]
-OH stretching vibrations (hydrogen bonds)3331[ , ]

Based on the knowledge of the structure of hemp fiber, its chemical and physical structure and properties, its possible application in various technical solutions is known. However, some applications require changing these properties. In order to modify them, in basic technological operations, these are mechanical modifications such as cutting or grinding. More advanced techniques that significantly change the properties, however, are based on chemical modifications such as alkalization, acetylation, esterification, silanization, acrylation, or through the use of carboxylic acids, anhydrides or solvent replacement. Each of the mentioned physical and chemical modifications causes a specific change in the properties of the hemp fiber and adjusts it to the most interactive use. This topic is explored more in-depth in the extensive work of Tanasa et al. [ 28 ].

2.1.2. Extract

Plants are the main source of natural extracts. Their matrix is used to extract all the natural compounds needed by humans, such as oils, essential oils, compounds with healing properties and others. Hemp, in this case, is also a rich source of these substances. In order to obtain them and collect the appropriate fraction, an appropriate extraction method should be selected. The literature indicates two main ones: the method with the use of organic solvents and the method with the use of supercritical gases. In the case of the first of them, one of the first steps is the comminution of the plant material and then treatment with a suitably selected organic solvent or their mixture at a predetermined temperature. The solvent flushes out specific compounds from the plant matrix as a result of its diffusion through its tissue. Unfortunately, this method suffers from a number of disadvantages, such as low selectivity, contamination of the extract obtained with residues of often toxic solvents, and the effect of high temperature as a factor causing the degradation of unstable natural compounds. The second method, i.e., the use of supercritical gases (most often carbon dioxide), is more innovative and allows avoiding the use of both elevated temperatures and organic solvents that are unfriendly to the natural environment. In this case, the solubility of active natural compounds that depend on such physicochemical factors as gas pressure, the temperature of the extraction process-by controlling these parameters, the gas diffusivity and polarity are controlled, which affects the solubility of the extracted substances. An additional advantage is that this process is carried out under inert gas conditions, which significantly reduces the oxidation of unstable compounds in the air atmosphere. Unfortunately, a small range of substances dissolves very well in supercritical carbon dioxide, which is why small amounts of other solvents are often used as cosolvents to help flush out the expected natural compounds from the matrix [ 63 ].

As the research conducted so far shows, over 500 active substances have been discovered in Cannabis Sativa , which can be classified into 18 main groups of chemical substances. Among other things, they are rich in 12 fatty acids, about 200 terpenes and 20 heterocyclic compounds containing nitrogen atoms in their ring structure, over 50 hydrocarbons and as many as 100 cannabinoids, of which hemp is the most famous. The main cannabidiols found in this plant include delta-9-tetrahydrocannabinol (THC), cannabidiol (CBD), cannabigerol (CBG), and cannabinol (CBN). The structures of the listed compounds have been collected and presented in Figure 2 . These salivae also contain various polyphenols with antioxidant properties, coloring compounds and polysaccharides [ 64 ].

An external file that holds a picture, illustration, etc.
Object name is materials-15-02565-g002.jpg

Structural formulas of cannabinoids occurring in hemp (CBD—cannabidiol; CBN—cannabinol; CBG—cannabigerol; CBC—cannabichromene; THC—tetrahydrocannabinol; THCV—tetrahydrocannabivarin).

Previous research in cannabis has discovered CBD was shown to have very strong antioxidant, anti-inflammatory and bactericidal properties and is used in anxiolytic, anticonvulsant and neurological therapies, while CBG also has analgesic properties. All of the mentioned compounds belong to the group of phytocannabinoids occurring depending on the variety and the way of cultivation in various quantities in cannabis. Cannabigerol is a precursor to the formation of compounds such as THC, CBD and cannabichromene (CBC). Unfortunately, THC, due to its psychoactive effects, has made cannabis infamous, as it contains a wide range of active, health-promoting natural compounds. CBD, CBC, and CBG are indicated as one of the main potential medicinal substances that can help people with diseases such as cancer, neurological diseases, bacterial infections and severe inflammation in the body. Strong healing properties are indicated even among drug-resistant bacteria, such as the Staphylococcus aureus strain. Hemp also contains various polyphenols with antioxidant properties, coloring compounds and polysaccharides [ 65 , 66 , 67 , 68 , 69 , 70 , 71 , 72 , 73 , 74 , 75 , 76 , 77 ].

2.1.3. Waxes

Waxes are still a little-known and studied part of the hemp plants. Its source may be hemp dust and waste generated during the processing of entire plants, fibers, seeds and leaves in various technological processes. This dust and waste is usually a waste product, but in the future, it may become a potential source of hemp waxes for use as an ingredient in cosmetics or as a natural polymer plasticizer [ 69 ]. They are part of the oil fraction which, according to the data contained in Table 2 given by L. Apostol in his article, has the following composition [ 78 ]:

Composition of the oily fraction derived from hemp seeds.

ComponentValue [%]
The content of the oily fraction in the entire mass of the hemp seed28.7
Palmitic acid6.96
Stearic acid2.74
Arachidic acid0.77
10.47
Oleic acid13.64
Linoleic acid56.35
Gamma-linoleic acid1.35
Alpha-linoleic acid17.30
Stearidonic acid0.50
Eicosenoic acid0.39
89.53

Attard et al., as a result of their research, performed an extraction using the supercritical carbon dioxide method and the Soxhlet extraction using heptane. In all the samples tested, they detected the presence of hydrocarbons, fatty acids, alcohols, fatty aldehydes, sterols, cannabinols and wax esters. The last of the mentioned groups of compounds were characterized by chain length from C 38 to C 58 . The most common wax ester in the samples was C 46 , and then C 44 . Interestingly, almost all wax esters were lost from hemp waste processed during paper production. The largest amounts of waxes were obtained as a result of supercritical extraction carried out at a temperature of about 50 °C and high pressure of 350 bar [ 69 ].

Other studies on cannabis samples by Francisco et al. showed the following chemical composition of the waxes obtained from the ethanol suspension [ 79 ]. These data are presented in Table 3 below.

The content of the fraction in the entire mass of the hemp waxes.

ComponentValue [%]
pentacosane1.92–2.17
heptacosane6.96–7.55
octacosane0.75–5.56
nonacosane9.92–10.51
triacontane0.44–0.58
dotriacontane0.49
tritriacontane1.58–2.06
pentatriacontane1.13–1.24
heptatriacontane1.18–1.23
sabinene0.31–0.51
p-cymene3.32–5.15
β-cubebene0.31–0.40
(−)-trans-caryophyllene5.90–7.22
β-copaene0.32–0.40
α-humulene0.51–0.94
(E,E)-β-farnesene0.30–0.33
γ-gurjunene0.27
γ-curcumene0.59–0.70
valencene0.51–0.60
germacrene A0.39–0.44
α-7-epi-selinene0.42–0.54
α-cadinene0.20–0.33
α-bisabolene1.63–2.50
(E,E)-α-farnesene0.28
dehydro-1,8-cineole1.23–1.99
isoborneol0.38
fenchone0.26–0.44
cis-thujone0.27
endo-fenchol0.26–0.28
cis-nerolidol2.50–2.84
trans-nerolidol0.43
caryophyllene oxide0.49–0.89
humulene epoxide II0.31–0.37
10-epi-γ-eudesmol0.61–0.82
1,10-di-epi-cubenol0.29–0.36
γ-eudesmol0.29–0.47
α-muurolol0.25–0.35
β-eudesmol0.67–1.01
α-bisabolol0.18
(2Z,6Z)-farnesol0.49
CBD4.20–9.67
CBC0.11–0.18
Δ -THC0.12–0.13
Δ -THC0.22–0.37
CBG0.07–0.22
CBN1.20–2.40
CBDA22.91–34.56
THCA5.78–5.89
heptanal0.22–0.61
2,4-hexadienal0.11
nonanal0.37
vanillin0.27
tridecanoic acid0.21–0.31
ethyl tetradecanoate0.42
hexadecenoic acid0.25–0.27
ethyl hexadecanoate0.22–0.31

As the research of the above scientists show, hemp waxes are rich not only in alkanes but also in monoterpenes, sesquiterpenes, terpenoids, but also in cannabinoids. This suggests that apart from the plasticizing and lubricating properties, the cannabis wax esters have strong healing and antioxidant properties. These products play a multi-functional role in their applications. However, these substances still require in-depth study because of the limited knowledge about them.

2.2. Sectors of the Economy Using Cannabis

The subject of the use of cannabis in science, industry or the arts has gained prominence in recent years. As can be seen from the Figure 3 below, the popularity of this keyword in the Scopus database has increased nearly 10-fold over the last 20 years. This indicates a remarkable interest, particularly since 2015, in this plant. The possibility of its use in a wide range of applications and the development of the pro-ecological trend in the world causes newer and more advanced research towards the description of properties and applications of hemp plants in everyday products.

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Change in the number of occurrences of the keyword “hemp” in the Scopus database in 2000–2021.

2.2.1. Agriculture and Energetic

Fiber hemp is a species of the annual hemp plant. These plants do not contain psychoactive substances; they are used in many industries, reaching a height of 1.5–3.5 m under favorable conditions. The main direction of the use of hemp in agriculture is the production of straw. As a result of processing the straw of mono-hemp fibrous hemp, we obtain 25–30% of the fiber and about 70% of the shives. Hemp is an interesting plant in terms of ecology and economy. Their cultivation does not require the use of plant protection products or pesticides, and hemp itself inhibits the development of weeds, repels pests, is resistant to diseases and requires only minerals contained in the soil. This has a positive effect on the environment as it contributes to the improvement of soil systems [ 80 ]. A suitable example is that these plants have a pile system root, which loosens and ventilates the soil and improves its water conditions, making it more beneficial for all plants that coexist with cannabis. This brings about positive effects, positively influencing the development of the economy, especially everything in agricultural countries. A favorable pro-ecological effect on the environment may, to some extent, reduce the need to increase expenditure on environmental protection and climate change. As indicated in the work of Żuk-Gołaszewska et al., one hectare of hemp plants is capable of absorbing about 2.5 tons of carbon dioxide [ 80 ]. Agriculture is the main and basic source of food, but despite this, it is not an economically competitive sector of the economy compared to other industries. Hemp straw in agriculture is used as a source of fodder with very good nutritional parameters for farm animals, mainly cattle. However, apart from that, it is also used as highly efficient biomass in the processes of generating both thermal and electric energy, which was presented in Figure 4 below [ 81 ].

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Processing cannabis for energy purposes.

2.2.2. Food Industry

One of the industries that use hemp is the food industry. Hemp food has been known for thousands of years and, at the same time, is a modern, fashionable and healthy food supplement containing valuable ingredients. The hemp seed based on which most hemp foods are prepared contains all of the amino acids and Omega 3, 6 and 9 fatty acids needed for the proper functioning of the human body, especially the brain, in appropriate proportions. About 35% of the seed content is easily digestible high-quality protein, but also contains dietary fiber to support the digestive system and proper digestion, as well as vitamins B and E. On the other hand, about 30% of the seed content is carbohydrates, providing energy for the body. Hemp seeds can be eaten raw, sprouted or powdered as flour. They are used for baking, as well as hemp milk made from them, similar to soy. About 27–38% of the seed weight can be extracted into hemp oil rich in unsaturated fatty acids, as Fike pointed out in his article [ 9 ]. The competition for hemp-based food products is the entire food market, especially organic food. Food products made on the basis of hemp have a positive health-promoting effect on our body. They affect cell regeneration, slow down the aging processes, inhibit the development of cancer cells and have a significant effect on immunity [ 9 ].

As Kaniewski pointed out in his work, hemp seeds are a rich source of edestin, phytic acid, choline, trigonelline, lecithin, chlorophyll, vitamin K and tocopherols, as well as many micro and macro elements such as iron, calcium, zinc, phosphorus, magnesium and vitamin E, which strong antioxidant properties. It protects unsaturated fatty acids against oxidation reactions, thanks to which they retain their properties. In addition, it has a positive effect on the circulatory system, making blood vessels more flexible, improving blood flow and reducing the possibility of ischemic heart disease or atherosclerosis [ 82 ]. Vitamin E is otherwise known as alpha-tocopherol (5.66% of all tocopherols). Cannabis also contains gamma-tocopherol (89.11%), beta-tocopherol (0.33%) and delta-tocopherol (4.90%). These are antioxidant compounds that are involved through the interaction and active quenching of DPPH and ABTS + cationic radicals. They form metal transfer chelates with them. They also absorb oxygen radicals generated by AAPPH (ORAC) and prevent lipid peroxidation in human LDL. Thanks to such good antioxidant properties, these compounds protect proteins, lipid membranes and DNA against the harmful effects of radicals that cause oxidative damage, as mentioned in the article by Żuk-Gołaszewska et al. [ 80 ]. Hemp food improves digestion and is beneficial for the healthy digestive system, and also lowers cholesterol, reducing the risk of heart attacks, one of the main civilization diseases of the 21st century in highly developed countries [ 78 ].

2.2.3. Textile Industry

The fibers obtained from Cannabis Sativa can be used to produce high-quality fabrics that are used in the clothing industry around the world. It is worth emphasizing that the production of hemp fibers is more ecological and less water-absorbing than the widely produced and used cotton. According to Columbia History of the World, hemp fabrics have been known to man since the eighth millennium BC. From the 5th century BC up to the stage of the industrial revolution, hemp fabrics were used in the production of about 90% of sails. Until the United States of America introduced the so-called Marihuana Tax Act (1937), which also included industrial hemp, about 80% of all fabrics intended for clothes and other everyday textile products were made of hemp fabrics. According to specialists in the textile industry, hemp fabrics are more durable and three times more extensible; they are warmer, more delicate and have high water absorption than cotton fabrics. One of Ireland’s exports from the decades to the 1930s was high-quality hemp-based underwear, while Italian hemp-based fabrics were considered one of the best textiles in the world. Hemp was also used to strengthen rotting and fire-resistant carpets, as opposed to artificial, flammable synthetics [ 69 ].

2.2.4. Pulp and Paper Industry

Another of the industries mentioned that uses industrial hemp is the pulp and paper industry. The first century AD saw the discovery in China that hemp paper is 50–100 times more durable than most papyrus varieties, and its production it is 100 times easier and cheaper. In the following years, this discovery spread all over the world, especially in Europe and America, where hemp paper was used to create bibles, banknotes, securities, navigation maps, logbooks, and in later years also, books and newspapers [ 83 ]. In 1776, the first declarations of independence for the United States were written on hemp paper, the popularity of which grew until the beginning of the 20th century and global industrial development. Until 1883, hemp paper accounted for most of the global paper market. Hemp has always been a significant competition in the present pulp and paper industry. Twenty to thirty percent of hemp stalks are made of hemp fiber, which is used to produce environmentally friendly paper. One hectare of hemp can produce 3–4 times more paper than the same area of trees, and the time of their growth is incomparably shorter and under favorable conditions, the harvest can take place even 3–4 times a year. Hemp paper, unlike wood pulp, does not require the clearing of long-growing, centuries-old forests that produce the oxygen necessary for life or such strong chemical processes that have a significant impact on the environment. The possibility of using recycled hemp paper is estimated at seven times, while the possibility of using wood for only three. The pulp and paper industry is one of the biggest competitors of the hemp industry, which, thanks to its political and economic influence, contributed to the introduction of the first cannabis prohibition in the United States and influenced the unfavorable perception of this plant in the world. In 1916, a method of producing hemp pulp for the production of paper was invented in the United States, using not the fibers of the stalks, as previously, but cellulose-rich fibers-shives, with four times higher efficiency, compared to wood production. The process could also use a much lower amount of sulfur and acid chemicals, and the hemp paper produced by this method does not require an environmentally harmful bleaching process. Unfortunately, no collection machines are available, and removing the outer shives from the inner fiber has not allowed this method to gain sufficient popularity. However, hemp is taking part in the production of paper again and again. As indicated in their article by Amode and Jeetah, paper production in 2018 was estimated at 400 million tons, and the annual growth each year until 2030 is forecasted at 1.1%. The data also allow the conclusion that by 2060 there will be an increase in the use of paper for printing and writing by as much as 180%. This information gives a signal that there is a need to use other sources of cellulose besides wood in the paper industry, and for environmental and ecological reasons, it will be worth increasing interest in hemp in this direction [ 84 ]. This is due to better product parameters, such as exceptional strength and mechanical and thermal resistance, resistance to abrasion and yellowing and high flexibility of the material [ 85 ].

2.2.5. Construction

Hemp is an extremely efficient and environmentally friendly building material. This is due to the fact that the increase in hemp biomass is two to four times greater than in forests managed on the same acreage. Hemp fiber is used to make furniture and decorations, partition plates are produced, thermal insulation of buildings is also carried out, or research is carried out on concrete blocks containing hemp fibers, characterized by low thermal conductivity and good acoustic barrier. From special varieties of hemp, it is easy to produce ecological bricks up to seven times stronger than concrete. Fiber hemp is also used to produce insulation material, building material for the construction of roofs, walls and floors. It is quite resistant to moisture, does not rot, is not flammable and is almost 100% recyclable. According to research by construction specialists, cellulose concrete made with hemp is resistant to fire and insects, is lighter than conventional building materials and has much better acoustic, thermal and insulating properties [ 86 , 87 , 88 , 89 , 90 ]. Seng et al. in their article, indicate that the thermal conductivity of hemp concrete, depending on the method, ranges from 0.103 to 0.112 W m −1 ·K −1 [ 88 ]. The use of hemp concrete reduces the cost of building a residential house thanks to the simplification of the structure and the use of cheaper raw materials. Other plant derivatives, such as hemp oil, can also be an important ingredient used in the manufacture of paints and varnishes, as it dries quickly and leaves a thin, flexible film, and the use of its subsidies in petrochemicals is eliminated.

2.2.6. Automotive Industry

Hemp influenced the development of the automotive industry from the very beginning. They were used in the first cars to produce structural elements. The fibers of this plant were tested as a component in the production of car bodies by Henry Ford in 1941 and by Lotus Cars. Hemp was also used to create laminates for any type of construction. Researchers dealing with the subject of hemp-containing materials postulate that hemp-based materials are extremely durable and at the same time have a high biodegradability potential. Many specialists present hemp as a natural material that is stronger than that obtained from other sources of natural cellulose fibers such as coconut, bamboo or jute. The prospect of biomaterials that make up motor vehicles is promising due to the high cost of storing old cars and a strong impact on the natural environment. The calculation of the impact of the entire product life cycle is emphasized. Hemp fiber is used to make body parts, cockpits, seats and other interior elements. On the other hand, the obtained hemp oil can be successfully used as a pro-ecological component of paints and varnishes [ 91 , 92 , 93 ].

2.2.7. Cosmetics, Pharmaceutical and Medical Industries

Recently, the use of hemp derivatives in the cosmetics industry has been a very fashionable direction. Hemp oil and extracts containing regenerative, anti-aging and anti-inflammatory substances are used in the production of hemp-based cosmetics. The concentration of the four main components in industrial hemp and wild hemp varied as follows: β-caryophyllene 11–22% and 15.4–29.6%, α-humulene 4.4–7.6% and 5.3–11.9%, caryophyllene oxide 8.6–13.7% and 0.2–31.2%, and humulene epoxide 2, 2.3–5.6% and 1.2–9.5%, respectively. The concentration of CBD in the essential oil of wild hemp ranged from 6.9 to 52.4% of the total oil content, while CBD in the essential oils of registered varieties ranged from 7.1 to 25%, as described in more detail in their article by Zheljazkov et al. [ 94 ]. It is applied directly to the skin, has a protective effect, soothes inflammation, irritation and skin changes, it is recommended for people with severe allergies. Beauty salons use hemp preparations as a moisturizing and nourishing agent, reducing discoloration and evening-out skin tone. Hemp oil belongs to the so-called dry oils because it is quickly absorbed and leaves no greasy film. It can be applied directly to the skin, but today many companies produce cosmetics based on it, including care creams, lotions, massage oils, soaps, shampoos, conditioners and more. Hemp extracts largely contain cannabidiol (CBD) and resin fractions that have soothing and calming properties. The pharmaceutical and medical industries also appreciate hemp ingredients more and more. Research is being carried out on the treatment of depression, sleepiness, convulsions, degenerative diseases such as Alzheimer’s disease and nutritional problems [ 95 ]. The latest reports also indicate strong antimicrobial properties, strong Gram-positive and Gram-negative effect on drug-resistant bacteria. Preliminary information also suggests possible inhibitory effects on the growth of cancer cells [ 94 , 95 , 96 ]. Recently, there have also been reports of the biggest problem at the moment, i.e., the SARS-CoV-2 pandemic. CBD contained in hemp was used on lung epithelial cells and in mice. Cannabidiol and its metabolite 7-OH-CBD strongly block viral replication by inhibiting gene expression and reversing the effects of infection. In this case, CBD inhibits SARS-CoV-2 replication in the early stages of the disease. This relationship is therefore indicated by Nguyen et al. as a very effective potential measure to prevent infection in the early stages of infection; however, further testing and clinical trials are needed to clearly confirm the effects of cannabidiol on this virus [ 97 , 98 ].

2.2.8. Polymer Industry

Currently, most branches of the economy are based on polymer products, but their negative impact significantly affects the degradation of the natural environment. For this reason, research is carried out, and newer, more environmentally friendly polymer composites are introduced to the market. Such are also composites based on hemp fibers. These fibers replace the previously commonly used glass fibers with reinforcing properties [ 99 ]. However, those used so far have been energy-consuming in the production process and difficult to utilize and non-biodegradable. On the other hand, replacing them with hemp fibers allowed for the creation of more environmentally friendly composites, which, after use, have a smaller impact on the environment during storage and are also subject to partial decomposition. The most popular biocomposites are those based on resins such as unsaturated polyester, phenolic or epoxy resins. They have found their application in the production of cars, hulls of boats and small airplanes, wind turbines and other objects made with the technology of creating laminates [ 43 ]. It is also possible to use hemp oils for the synthesis of polymers, but so far, it is a poorly developed branch. A new approach indicated in the research work of Dr. Masek’s group is the use of hemp extracts and waxes in composites based on biothermoplastics and ecological vulcanizates. The hemp compounds mentioned are used as dyes, indicators of degradation processes, inhibitors and catalysts of aging processes [ 63 , 100 ].

2.2.9. Other Uses

Interesting and worth mentioning and emphasizing is the possibility of using hemp plants for the rehabilitation of mining excavations. These plants, due to their good adaptation to environmental conditions, high resistance to pests and diseases, are a great organism for pioneering introduction to damaged heaps and post-mining areas. They have good properties of binding heavy metals in their structure, which significantly allows the soil to be cleaned in a short and ecological way and enables the introduction of other species of fauna and flora to the reclaimed ecosystem [ 82 , 83 , 101 ].

The Figure 5 attached above gives a good indication of the fields in which interest in hemp plants has been greatest over the last 10 years. The top five with the highest number of publications on them are material science, engineering, agricultural and biological sciences, chemistry and chemical engineering. This analysis shows very interesting data, as the general opinion of the average consumer is that the greatest use of hemp is in cosmetology, pharmaceuticals and the medical industry, less so in the food industry. However, the data presented show that it is the industry, especially the materials industry, that has the greatest aspirations for the use of these plants in science and industry. As illustrated in Figure 6 below.

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The number of occurrences of the phrase “hemp” in the Scopus database in the last 10 years, broken down into individual fields (as of 5 December 2021).

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The use of hemp in various industries due to the division into the parts of the plant used.

3. Hemp and Derivatives in the Polymer Industry

Polymers are the most important construction material of the 20th and 21st centuries in many industries around the world. However, their cheapness and durability caused enormous havoc on the natural environment due to the deposition of huge heaps of rubbish on land and huge islands of artificial plastic seen even from space in the ratings. For this reason, the industry of biodegradable polymers and creative composites made of these polymers with natural additives has been rapidly developing in recent years. As can be seen from the above-mentioned examples of applications and the specified chemical compositions and physicochemical properties of hemp and its derivatives, these plants are an ideal candidate for a huge share in this industry sector.

3.1. Thermoplastics

Thermoplastics are currently the largest group of manufactured polymers. They have such advantages as the possibility of material, raw material or energy recycling. Over the past decades, new types of thermoplastics were developed that are made from renewable green sources and are biodegradable. Unfortunately, many of these materials do not have the required physical or chemical properties as well as conventional fossil-based thermoplastics [ 102 ]. Such conventional polymers are polypropylene (PP) and polyethylene (PE). They are characterized by durability, stiffness, lightness, good barrier properties; they are satisfactorily chemically inert, easily processable and, above all, cheap. These features make them one of the most commonly used polymers in everyday life for the production of packaging, everyday equipment and construction materials. However, these are non-biodegradable polymers; in order to increase the potential of products made of them for biodegradation and to reduce their mass proportion in the product, natural fillers are also introduced to strengthen the mechanical properties [ 103 ]. Hemp fibers can be an excellent filler in this case. This is emphasized in their work by Sullins et al. [ 104 , 105 , 106 ]. The addition of modified hemp fibers for modified hemp fibers to the PP composite increased its flexural and tensile properties. The composite with up to 30% of fibers showed better properties than pure polymer or content of 15%. Hemp fibers also showed very good interfacial interactions with this polymer matrix. On the other hand, Etaati et al., in their research, indicated changes in the analysis of dynamic mechanical properties. They investigated changes in these properties of polypropylene composites with short hemp fibers at temperatures from 25 to 150 °C. They indicate in their article that the addition of fibers strengthens the composite when working at higher temperatures, above alpha relaxation. They also emphasize that when more modifications are used in the form of a coupling agent, it is also required, which confirms the earlier statement about the necessity to modify the fibers and the composites formed with them [ 107 , 108 ]. Researcher Oliveira et al. instead dealt with PE-based composites. In her research, she showed that the treatment of hemp fibers with alkali in order to flush out lignin and hemicellulose improved the dispersion of these fibers in the matrix and improved resistance to thermal degradation. The addition of 5% modified hemp fibers and the use of a bonding agent also improved the processability during rotational molding [ 109 ]. The introduction of hemp allows lowering or eliminating voids altogether and creates stronger connections at the fiber-polymer matrix boundary, thanks to which it does not change the strength, while the modulus of elasticity increases material. Additionally, such composites characterize a more hydrophilic surface that can affect their faster degradation and thus facilitate the recycling of polyethylene-based products [ 110 ]. The most frequently used biodegradable polymer composites with hemp fibers are those based on polymers of aliphatic polyesters such as polylactide (PLA) or polyhydroxybutyrate (PHB) [ 99 , 111 , 112 , 113 ]. In the case of these polymers, the addition of hemp fibers accelerates hydrolytic degradation, which is worth mentioning that such material decomposes faster in the environment into simple compounds such as water, carbon dioxide and biomass. According to Mazzanti et al., even such a small addition of 3% wt. causes this effect [ 114 ]. As for PP and PE, also for PLA, the addition of hemp fibers significantly enhances the mechanical and thermal properties of such refined compositions. Differential Scanning Calorimetry (DSC) studies indicated that the addition of fibers did not significantly affect the glass transition and melting temperatures [ 115 ]. At this point, it is also worth emphasizing that in the case of using such a filler as hemp fibers, it depends on the orientation of the material. Arrangement parallel to the force of the fibers leads to a strong effect of transferring stresses inside the material; therefore, an important stage in the preparation of polymer composites with them is their proper orientation through the use of appropriate unit operations in the process, such as rolling, extruding, injection or calendaring. This approach allows the best possible use of the fibers as an active filler in polymer composites [ 116 , 117 ]. Apart from fibers, hemp extracts are also other additives to thermoplastic polymers. Thus far, this is a supplement with antioxidant properties. In his work, Plota et al. showed the thermally stabilizing effect of CBD on polylactide and Topas. In this case, the indicative effect of this additive is also indicated, as the color of refined samples changed with the aging processes. This is one of the few works in this direction worth exploring [ 118 ]. An equally interesting approach was shown by a team of researchers led by Andriotis et al. They created water-soluble fibers produced by the electrospun method using polyvinyl (pyrrolidine) (PVP) and Eudragit L-100, in which CBD and CBG were used as active substances with therapeutic effect [ 119 ]. Thermoplastic composites using hemp materials, as you can see, are in common use and find more and more possible applications in everyday life as well as in construction materials. It is worth continuing research on this type of material in order to increase their share in green polymer composites.

3.2. Elastomers

Rubbers are another important material used by humans. Due to cross-linking, unfortunately, they are not recyclable, and their natural decomposition takes hundreds of years. For this reason, it is worth delving into and developing intensively more environmentally friendly rubber compounds. In this case, hemp materials can also help us. Previous studies indicate the use of hemp derivatives in mixtures based on natural rubber (NR) [ 120 ]. From the results obtained by Moonart et al., it follows that in order to obtain good adhesion between the fiber and the polymer matrix, they must be treated. In this case, it was proposed to prepare by treating the hemp fiber with alkali and then using a KMnO 4 solution and silane. Such modification resulted in an increase in the tensile strength of the fibers and a better interfacial connection of the materials [ 121 , 122 ]. Another study investigated NR vulcanizates with hemp fibers cross-linked with benzoyl peroxide. This arrangement exhibited increased hardness, modulus at 100% elongation, tear strength, tensile strength and elongation at break. This effect depended on the degree of fiber filling of the composite. Hemp fibers can be, in this case, a good replacement for synthetic or steel fibers due to their cheapness, biodegradability and good weight-to-strength ratio [ 123 ].

3.3. Duroplasts

Duroplasts are the last group of the polymeric materials we discuss with conspicuous additives [ 124 ]. One of the most commonly used thermosets is unsaturated epoxy resins [ 41 , 53 , 125 , 126 , 127 , 128 , 129 , 130 ]. It is this polymer that is one of the most modified with hemp derivatives. As a result of the addition of fibers, the tensile, compressive and bending strengths increased. It is logical because the fibers perfectly transfer stresses in materials in which they are active fillers. Modification by copolymerization involving the grafting of acrylonitrile on the surface of the fibers also allowed for a minimal improvement in thermal stability than in the case of unmodified hemp fibers [ 108 , 131 , 132 ]. In his article, Scarponi compared the use of glass and hemp fibers [ 133 ]. They showed that hemp/epoxy composites could compete with glass/epoxy composites. The covers for ultra-light airplanes produced for the purpose of the tests showed very good properties and, at the same time, greater environmental friendliness [ 134 ]. As indicated by previous research and theory, natural fibers require some modification to improve compatibility with the polymer matrix. In the case of combinations of hemp fibers with unsaturated polyester resin (UPE), esterification of the fibers is a good example. Such an operation allows to significantly improve the interfacial adhesion, as a result of which the chemical resistance but also the mechanical and thermal resistance of the obtained composites is improved. Another popular polymer matrix of hemp composites is polyurethanes. Members et al., in their publication, showed that the addition of hemp derivatives influenced such properties of polyurethane foams as morphology, mechanical, thermal and insulating properties. They showed in their work that impregnation with sunflower oil and tung oil resulted in improved thermal stability and flame retardancy of PUR foams. It reduced hydrophilicity by limiting water absorption [ 135 ]. Materials such as PUR are used in the construction industry to improve the thermal insulation properties of buildings. The introduction of the hemp filler brings us closer to a more sustainable development of this industry sector. Hemp fibers added to polyurethanes in the amount of 15% by weight will increase the tensile and bending modulus. Such an addition makes the product more environmentally friendly and reduces its cost [ 136 , 137 ].

4. Conclusions

This overview article shows how important cannabis has been in human history so far and what it may be in the future. The contained data illustrating the richness of the chemical composition of these plants indicates the possibility of the very wide use of active compounds in medicine, pharmacy, cosmetology and the food industry. Interest in these plants is already growing in these sectors. The use of hemp and its derivatives in the new materials sector also shows promise for the development of environmentally friendly polymer products. The polymer industry, contributing to each of the main sectors of the economy, can draw from this green source of many active phytosubstances, oils and fibers. The pro-ecological aspect of hemp cultivation, low soil and water requirements and the possibility of processing and using 100% of plants with cheap production allow us to be optimistic about the development of this production department and related science activities. There is also a lack of basic knowledge in the use of other cannabis derivatives in the polymer industry. The section dealing with elastomers is the poorest in the literature on this subject. It is a signal for researchers, technologists and entrepreneurs with a possible niche to research and use this valuable source of substances, not only fibers as a strengthening additive but also extracts and waxes as an antioxidant, antimicrobial substances, plasticizers and aging time indicators. In our opinion, scientists from around the world should intensify research on environmentally friendly materials such as hemp, which is the material of the future.

Acknowledgments

This work was completed while the second author was a doctoral candidate in the Interdisciplinary Doctoral School at the Lodz University of Technology, Poland.

Abbreviations

AAPPH (ORAC)Oxygen Radical Absorbance Capacity
ABTS2,2-azinobis-(3-ethylbenzothiazoline-6-sulfonate)
CBCCannabichromene
CBDCannabidiol
CBDACannabinoid acid
CBGCannabigerol
CBNCannabinol
C-NMRCarbon-13 (C13) nuclear magnetic resonance
DPPH2,2-diphenyl-1-picrylhydrazyl.
FT-IRInfrared Spectroscopy with Fourier Transformation
NaOHSodium hydroxide
THCDelta-9-tetrahydrocannabinol
THCVTetrahydrocannabivarin

Author Contributions

Conceptualization, formal analysis, data analysis, investigation, methodology, review and editing, A.M.; data analysis, investigation, methodology and writing, K.T.; description of results, methodology, data analysis, investigation and writing K.T.; supervisor A.M. All authors have read and agreed to the published version of the manuscript.

No external funding provided.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Data availability statement, conflicts of interest.

The authors declare no conflict of interest.

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Industrial hemp fiber: A sustainable and economical alternative to cotton

  • Journal of Cleaner Production 268:122180

Ana Duque at Rensselaer Polytechnic Institute

  • Rensselaer Polytechnic Institute

Sergio Pequito at Delft University of Technology

  • Delft University of Technology

Jennifer A. Pazour at Rensselaer Polytechnic Institute

Abstract and Figures

for the map of countries allowing the growth of hemp as of 2019). Note that not all the states in the United States (US) allow hemp cultivations.

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Explained – How Hemp Paper is Produced

hemp paper case study

[vc_row][vc_column][vc_column_text]Paper produced entirely or mostly from the fibers of the hemp plant is known as hemp paper . Hemp or industrial hemp is the non-narcotic kin of drug cannabis or marijuana. Hemp belongs to the same plant species Cannabis Sativa L as marijuana. It’s difficult to understand how hemp paper is produced unless you understand the history of it because the method has evolved over the decades. This botanical relationship had led to hemp being outlawed in much of the world in the 20th century. Thankfully, many countries have now corrected this human blunder. Hemp has been decriminalized since it does not possess any psychoactive properties. Tetrahydrocannabinol (THC), the psychoactive element is present in high concentration in drug cannabis: 7.5 to 10 percent or higher. This gives marijuana its capacity to cause the so-called high. THC presence is limited to 0.3 percent or less in hemp, which means this plant has no psychotropic effects.[/vc_column_text][/vc_column][/vc_row][vc_row][vc_column][vc_column_text]

Hemp Paper Antiquities

Historians inform us that the world’s earliest paper was made by the Chinese from hemp fibers nearly 2,200 years ago around 150 BCE. It spread from China to the Middle East and then to the rest of the world. All paper used in the world was hemp paper till 1883. The first printed Bible, known as the Gutenberg Bible or the 42-line Bible, used hemp paper. Mark Twain’s novels also got printed on hemp paper. It was hemp paper that Thomas Paine used to print the leaflets that spread the idea of American independence. The first two drafts of the American Declaration of Independence were written on hemp paper. The first version of the US Constitution also got drafted on hemp paper. The current usage of hemp paper, however, is restricted mostly to specialty paper. [/vc_column_text][tm_image align=”center” md_align=”center” image=”10694″][vc_column_text]

Ancient Chinese paper

[/vc_column_text][/vc_column][/vc_row][vc_row][vc_column][vc_column_text]

How Hemp Paper Is Made Today?

Fibers sourced from hemp stalks are among the strongest plant fibers in tensile strength. Hemp stalks yield two types of fibers: long bast fibers and short hemp hurds or pulp fibers. Longer bast fibers come from the outer layer of the hemp stem while hemp hurds refers to the woody inner core.

It is possible to use both types of fibers for the production of hemp paper. Paper made from the long bast fibers is crumbly, thin, and coarse. Paper made from hemp hurds or pulp is thicker and softer. The production process of paper from hemp pulp is also easier.

Hemp paper like traditional paper needs the pulping of the fibers into a slurry. This is easier to do using hemp hurds. The first step is to separate the pulp from other plant matter. The next step is to soak the refined pulp in clean water and pound it to get a pulp slurry.

In industrial papermaking, some additives are used for the slurry. The next step is to remove the excess water from the slurry. The paper machine spreads the slurry on a mobile continuous screen for the water to be drained by gravity or vacuum.

Then the wet paper goes through pressing to be dried. The final outcome is a roll of paper. Cutting the rolls into different paper sizes using mechanized cutters is often a separate enterprise that paper mills do not undertake.

One of the major differences between handmade paper and industrialized paper constitutes in the edges. The machine-cut paper has smooth edges. Wooden frames called deckles are used to cut the paper into different sizes in handmade paper. That leaves the edges slightly uneven. Known as deckle-edges, they indicate that the paper is handmade.[/vc_column_text][tm_image align=”center” md_align=”center” image=”10695″][vc_column_text]

Producing handmade hemp paper

Benefits of Hemp Paper

Knowing how hemp paper is made isn’t enough. You need to know the benefits.

Hemp remained the primary source of papermaking for 2000 years until wood pulp substituted it in the 20th century. The renewed interest in using hemp for papermaking is a result of a growing consciousness about several environmental hazards of using tree paper.

Hemp is nature’s solution to all the problems associated with the use of wood paper. Hemp has considerably higher renewability than trees as a source for paper. The quantity of paper generated from one acre of hemp is equal to what four to 10 acres of trees can produce over a period of 20 years.

The reason behind this productivity is the higher cellulose content in hemp stalks. Cellulose is the main ingredient of paper. Hemp stalks contain up to 85 percent cellulose in comparison to about 30 percent cellulose in wood.

The use of chemicals to remove the non-cellulose contents is significantly higher in the case of wood as nearly 70 percent of the wood is non-cellulose. Also, trees need 20 to 80 years to mature. Hemp, in contrast, is ready for use in four months.

Hemp paper is also significantly more durable than paper produced from wood pulp. It does not yellow and cracks as easily as wood paper. Ancient remnants of hemp paper testify to its durability. Hemp paper is a natural substitute for the special acid paper used for conserving important documents.[/vc_column_text][/vc_column][/vc_row][vc_row][vc_column][vc_column_text]

Hemp Paper and the Environment

If Mother Earth had a choice, she would choose hemp paper over wood paper. Hemp paper is far more environmentally-friendly than tree paper. Deforestation is a case in point. The world lost 502,000 square miles or 1.3 million square kilometers of forest cover between 1990 and 2016.

The National Geographic published this data quoting a World Bank report. The effects of deforestation are grim and far-reaching. It is one of the primary causes of global warming and climate change . To destroy a forest is also to release the carbon dioxide sequestered there into the atmosphere.

In addition, fewer trees imply a reduced capacity for carbon dioxide absorption. Forests are also critical for the natural water cycle to be maintained. Further, there is the loss of natural habitats for a wide range of flora and fauna. That endangers their existence and threatens the planet’s natural biodiversity.

Using hemp instead of trees for papermaking is one eco-friendly response to the problem of deforestation. In addition to reducing the need to fell trees, hemp also regenerates the soil. Paper companies planting eucalyptus after felling all the trees in an area does not compare with hemp.

Another environment-friendly aspect of hemp paper is that it needs no bleaching. The production of hemp paper thus eliminates the chances of contaminating water with dioxin or chlorine, as paper mills do. The chemicals used in separating hemp fibers from the lignin are far less toxic.

The only plant better suited for papermaking than hemp is kenaf. However, kenaf does not grow as fast as hemp and does not produce as much fiber as hemp does. Hemp has the potential to meet all our paper needs, but kenaf does not.[/vc_column_text][/vc_column][/vc_row][vc_row][vc_column][vc_column_text]

How Hemp Paper is Made: Present and Future

Contemporary use of hemp paper is mostly limited to the production of specialty paper such as cigarette paper and cosmetic tissue paper. Only a few companies in Europe and North America have experimented with producing writing paper from hemp.

One of the reasons behind the resistance to using hemp as a source for writing paper could be the costs involved in changing the machinery. About 40 to 60 percent of retooling is necessary to switch from tree paper to hemp paper.

Gmund, a large papermill in Germany is increasingly producing large batches of hemp paper varieties, including writing paper. Other paper mills around the world need to undertake the equipment change to produce more hemp paper unless we want to be left with no more trees to fell.[/vc_column_text][/vc_column][/vc_row]

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Congress Advances Cannabis and Hemp Proposals

  • The U.S. Congress is moving forward with legislation that will change the regulation of hemp-derived products.
  • The hemp-derived cannabinoid market, conservatively valued at nearly $30 billion, could see changes as early as this fall, although it's more likely to be in the first quarter of 2025.

Recent congressional activity highlights the changing environment for cannabis regulation. Specifically, U.S. Congress is moving forward with legislation that will change the regulation of hemp-derived products. The industry could see changes as early as this fall, although it's more likely to be in the first quarter of 2025.

The Farm Bill Reauthorization

The Agriculture Improvement Act of 2018 (the 2018 Farm Bill) amended the Controlled Substances Act (CSA) to exclude certain products from the definition of marijuana. Specifically, the Act defines hemp as "the plant Cannabis sativa L. and any part of that plant, including the seeds thereof and all derivatives, extracts, cannabinoids, isomers, acids, salts and salts of isomers, whether growing or not, with a delta-9 tetrahydrocannabinol (THC) concentration of not more than 0.3 percent on a dry weight basis."

This definition in the 2018 Farm Bill removed hemp with 0.3 percent or less of THC from the CSA, which in practice means that cannabidiol (CBD) that meets the definition of hemp is not considered a controlled substance. Although Congress' intent is generally understood to have been the legalization of hemp production (for textiles and nonintoxicating supplements) for the first time in more than a century, the 2018 Farm Bill language admittedly did not foresee the creation of the hemp-derived cannabinoid market, now conservatively valued at $28.4 billion. 1

The Farm Bill is now up for reauthorization, which happens approximately every five years. The U.S. House of Representatives' version of the 2024 Farm Bill contains language that modifies these provisions. Specifically, it now contains provisions that clarify the types of hemp cannabinoid products that would be considered lawful. The bill would redefine the existing statutory definition of hemp by replacing language basing the legal limits for hemp on its delta-9 tetrahydrocannabinol (delta-9 THC) concentration and instead basing the definition on hemp's "total tetrahydrocannabinol (including tetrahydrocannabinol acid (THCA]) [Total THC] concentration." Other statutory language regarding hemp "derivatives, extracts, cannabinoids, isomers, acids, salts, and salts of isomers, whether growing or not" would remain unchanged.

In addition, at the House Committee on Agriculture's late-May markup of the Farm Bill reauthorization language, an amendment was passed that changed the definition of hemp in federal law to only include naturally occurring, naturally derived and nonintoxicating cannabinoids. (See Holland & Knight's previous alert, " House Agriculture Committee Completes Markup of 2024 Farm Bill ," May 28, 2024.) The bill as amended does not define "intoxicating," however, it would prohibit hemp cannabinoid products with "quantifiable amounts" of Total THC (including THCA) or any other cannabinoids that have (or are marketed to have) "similar effects on humans or animals" as THC, as determined by the U.S. Department of Agriculture (USDA).

Although the U.S. Senate version of the 2024 Farm Bill has not yet been released, it is clear Congress is looking to resolve, in some fashion, issues related to THC production resulting from the 2018 Farm Bill.

Fiscal Year 2025 Appropriations Bills

The Agriculture-FDA Appropriations legislation for fiscal year 2025 also contains language addressing hemp. The House bill contains language similar to the 2024 Farm Bill proposals that further refines the federal definition of hemp to only include naturally occurring, naturally derived and nonintoxicating cannabinoids and excludes those with "quantifiable amounts" of Total THC.

The recently released Senate version of the Agriculture-FDA funding bill contains no provisions related to hemp and cannabinoids. The full Senate will vote on the bill in the coming weeks. Provisions could be added when the bill is debated by the full Senate, but the most likely outcome is that House and Senate negotiators will work toward finding a solution before final passage this year.

Congressional action on the Farm Bill and the appropriations process are significant because they become effective upon enactment – which could be as early as this fall. Thus, they will become legally binding before the U.S. Drug Enforcement Agency (DEA) publishes its final regulation on the rescheduling of marijuana.

Holland & Knight will continue to closely monitor these developments. Please contact the authors for more information.

1 2023 U.S. National Cannabinoid Report , Whitney Economics

Information contained in this alert is for the general education and knowledge of our readers. It is not designed to be, and should not be used as, the sole source of information when analyzing and resolving a legal problem, and it should not be substituted for legal advice, which relies on a specific factual analysis. Moreover, the laws of each jurisdiction are different and are constantly changing. This information is not intended to create, and receipt of it does not constitute, an attorney-client relationship. If you have specific questions regarding a particular fact situation, we urge you to consult the authors of this publication, your Holland & Knight representative or other competent legal counsel.

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Planetary Politics

Impact hub case studies: cross-sector institutions solving public problems, apopo, singapore’s alliances for action, and the guinea worm eradication program, policy paper.

hemp paper case study

Aug. 2, 2024

In an effort to support policymakers and civic entrepreneurs around the world, New America and the Chandler Institute of Governance in Singapore are conducting research to better understand the features of cross-sector institutions that can solve public problems.

One model is an Impact Hub, a type of institution that brings together diverse partners to address a specific, clearly defined policy challenge. Impact Hubs pool the expertise, resources, and networks of partners from the public, private, and civic sectors. They implement concrete solutions and use metrics to track outcomes. The Impact Hub Field Guide describes their features in detail and the steps for shaping one.

Several hubs are already operating at the global, national, and local levels all over the world. A new collection of case studies examines three of these hubs in depth: APOPO, Singapore’s Alliances for Action, and the Guinea Worm Eradication Program.

In order to reduce civilian harm from the millions of landmines in post-conflict zones all over the world, APOPO , a Belgian-based nonprofit, implemented a novel, cost-effective method: trained scent-detection rats. To find both landmines and cases of tuberculosis, the organization used an innovative operational model based on local partnerships, technological innovation, and community engagement to deploy rats at scale and save thousands of lives.

Alliances for Action

In order to develop and implement solutions to a range of local challenges, the Singaporean government partnered with companies, civil society organizations, and citizens to create Alliances for Action (AfA). These time-bound, results-based initiatives built civic ties and made measurable progress on issues ranging from environmental protection to online harms.

Guinea Worm Eradication Program

The Guinea Worm Eradication Program (GWEP) brought together partners ranging from presidents to village elders to prevent the spread of the Guinea Worm disease, a painful, debilitating ailment that affects people in some of the world’s most isolated and lowest-income areas. In 1986, when the Carter Center, a U.S. nonprofit organization, started its initiative to address the disease, 3.5 million people suffered from it. In 2023, the world recorded only 14 cases, with the disease on the verge of being only the second ever to be eradicated (after smallpox in 1980).

IMAGES

  1. Scheme of (a) hemp paper preparation, (b) paper lamination process

    hemp paper case study

  2. Explained

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  3. Top 10 Research Papers On Hemp

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  4. Hemp Paper: A Comprehensive Guide

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  5. Hemp Paper: Everything You Need to Know

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  6. [PDF] Processing of Industrial Hemp into Papermaking Pulps Intended for

    hemp paper case study

VIDEO

  1. 2016 SLAS Past Paper

  2. Cultivating Success: A Year in the Life of an Industrial Hemp Farmer in Australia

  3. Hemp Tribe OrthoGo

  4. 2023 GS IV Ethics paper

  5. Class 12th math , previous year paper CASE STUDY ,Recent studies suggest that roughly 12 .by J.P Sir

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COMMENTS

  1. Case Report Knowledge mapping for a secure and sustainable hemp

    Case Studies in Chemical and Environmental Engineering. Volume 9, June 2024, 100550. ... In this context, we systematically reviewed 101 reviews and 655 research papers on hemp to map what we already know and what we still need to know about hemp, across its supply chain; from cultivar selection through production to end use. ...

  2. Hemp as a potential raw material toward a sustainable world: A review

    According to the study on different pulping methods of hemp bast fiber, it is found quite acceptable in place of wood from the technical point of view, and even woody cores can also be a promising raw material for paper. Hemp pulps are generally used by mixing with wood pulp, and currently, 100% hemp paper production is not seen [41]. Hemp is ...

  3. Environmental Life Cycle Assessment of a Novel Hemp-Based Building

    Similarly to its main component, the CF of LHC varies across regions [] (Table 2).Most LCA studies have also reported that LHC has the potential to be a carbon negative material [18,20,21,29,30,31], and highlight the production of lime-based binders as a hotspot during its life cycle [9,32,33].Moreover, when large amounts of lime-based binders are used, the resultant material tends to be ...

  4. (PDF) Evaluation of the Environmental Sustainability of Hemp as a

    State of the art: studies on hemp in the b uilding sector Several studies r elated to hem p - based products employed in the bui lding sector were carried out during the last 15 years.

  5. A comprehensive review on the use of hemp in concrete

    2024, Case Studies in Chemical and Environmental Engineering. Show abstract. ... In this context, we systematically reviewed 101 reviews and 655 research papers on hemp to map what we already know and what we still need to know about hemp, across its supply chain; from cultivar selection through production to end use. ...

  6. The Sustainability of Industrial Hemp: A Literature Review of Its

    As is the case for many other industrial plant species, hemp economics is complex. ... which it is grown and refined; it can be a carbon neutral or carbon negative plant, depending on these methods. In one study, hemp straw grown on a 2.47-acre field ... D.G. Industrial Hemp as an Alternative Crop in North Dakota: A White Paper Study of the ...

  7. Hemp Concrete

    Hemp concrete is a lightweight concrete that is currently only being used as an in-fill material. in non-structural applications (see Figure 2). In European countries it is normally cast in ...

  8. Consumer response to hemp: A case study of Vermont residents from 2019

    Familiarity with hemp paper has risen from 35.0% in 2019 to 61.6% in 2020. General use of hemp-based products has risen from 32.6% in 2019 to 54.7% in 2020. ... Through a case study of Vermont residents, results offer a reference for consumer response and behavior toward hemp in the first year of federal legalization.

  9. PDF Hempcrete Buildings: Environmental Sustainability and Durability of Two

    this paper will be implemented with periodical tests to study the evolution of the performances of the material and its durability in residential structures. The main concern about the durability of hempcrete is determined by the presence of vegetal material because the variation of moisture conditions can cause its degradation. Thus, a

  10. Sustainable Development: Building a Case for Hemp

    Department of Textiles and Consumer Sciences. Tel: (850) 644 -8078, Fax: (850) 645-4673. E -mail: [email protected]. ABSTRACT. Objectives of this paper are to discuss hemp within the ...

  11. Marketing potentials of ecofriendly paper products: case study

    The ecofriendly or green revolution has greatly evolved, especially from a marketing perspective. Hemp products, especially food protein and non-food products (paper) may well be the next evolution ecofriendly supply chain strategies. Through the use of a case study approach, hemp as a source for paper that results in a quicker cycle time and is more climate change friendly than trees, may ...

  12. Hair Regrowth with Novel Hemp Extract: A Case Series

    A 2021 case study of CBD-rich hemp extract revealed 93.5% average increase in hair regrowth. Hemp extract works through the endocannabinoid system (ECS) in the body and has novel effects on hair follicle elongation and hair matrix keratinocytes activated through ECS receptors in the hair follicle cells. As such, the therapeutic effects of hemp ...

  13. Opportunities & challenges of hempcrete as a building material for

    Sustainable construction materials, environmentally friendly materials, hemp, and hempcrete were used as keywords for literature research. For the research paper, papers published from the past 10 to 15 years with a few older studies were also included. various articles, YouTube videos and journals were also being considered for the same.

  14. [PDF] Hemp in the United States: A Case Study of Regulatory Path

    This study describes what is known about the economic and regulatory considerations of U.S. hemp agriculture through the lens of path dependency, and important questions remain regarding the legal and regulatory landscape of hemp, and are further complicated by its current listing as a Schedule 1 drug. The Agricultural Act of 2014 allowed for federally funded research on hemp for the first ...

  15. Resources

    Click on the button or image to read and download the IHBA Position Paper from February 2022 on The Appropriate Measurement of Hemp and Other Natural Building Material Performance. Download. Other resources on hemp building. Print Book. Hemp Buildings: 50 International Case Studies . by Steve Allin, order the book from the Seedpress website ...

  16. Article: Marketing potentials of ecofriendly paper products: case study

    Hemp products, especially food protein and non-food products (paper) may well be the next evolution ecofriendly supply chain strategies. Through the use of a case study approach, hemp as a source for paper that results in a quicker cycle time and is more climate change friendly than trees, may well turn out to be a part of a sustainable supply ...

  17. Hemp and Its Derivatives as a Universal Industrial Raw Material (with

    Until 1883, hemp paper accounted for most of the global paper market. Hemp has always been a significant competition in the present pulp and paper industry. ... In this case, hemp materials can also help us. Previous studies indicate the use of hemp derivatives in mixtures based on natural rubber (NR) . From the results obtained by Moonart et ...

  18. A comprehensive review on the use of hemp in concrete

    Hemp concrete is a "carbon-negative" or "better-than-zero-carbon" substance because the hemp plant absorbs more carbon from the atmosphere than it emits during its production and application on site. It is a bio-composite material that can be utilised as an alternative to concrete and standard insulation in building.

  19. Hemp as a potential raw material toward a sustainable world: A review

    According to the study on different pulping methods of hemp bast fiber, it is found quite acceptable in place of wood from the technical point of view, and even woody cores can also be a promising raw material for paper. Hemp pulps are generally used by mixing with wood pulp, and currently, 100% hemp paper production is not seen

  20. (PDF) Industrial hemp fiber: A sustainable and economical alternative

    Papers focused specifically on hemp fiber, like the influence of weave patterns and features (Corbin et a l., 2020), have enab led introduction into the industry. Th at being said, U S pilot studies

  21. Explained

    Paper made from the long bast fibers is crumbly, thin, and coarse. Paper made from hemp hurds or pulp is thicker and softer. The production process of paper from hemp pulp is also easier. Hemp paper like traditional paper needs the pulping of the fibers into a slurry. This is easier to do using hemp hurds.

  22. A review of the properties of hemp concrete for green building

    This paper presents a review of the state-of-the-art of hemp concrete research, with a view to identifying research gaps that shall guide future research for its implementation in the fast-growing green buildings industry. ... no larger than 40 ± 5 mm in their largest dimension. Sinka et al. (2014) in their studies had used hemp hurds having ...

  23. Congress Advances Cannabis and Hemp Proposals

    Case Studies. View All Matching Results; July 26, 2024. Congress Advances Cannabis and Hemp Proposals. ... Substances Act (CSA) to exclude certain products from the definition of marijuana. Specifically, the Act defines hemp as "the plant Cannabis sativa L. and any part of that plant, including the seeds thereof and all derivatives, extracts ...

  24. Impact Hub Case Studies: Cross-Sector Institutions Solving Public Problems

    In an effort to support policymakers and civic entrepreneurs around the world, New America and the Chandler Institute of Governance in Singapore are conducting research to better understand the features of cross-sector institutions that can solve public problems.. One model is an Impact Hub, a type of institution that brings together diverse partners to address a specific, clearly defined ...